WebThe role of β-branching in T2EHDGA was previously discussed as the hypothesis for this decrease in number of DGAs per Ln as well as distribution coefficient. In the presence of phase modifiers, TODGA and T2EHDGA interact with Ln similarly to without phase modifiers when comparing differences observed between HNO 3 and HCl systems. This ... WebJun 18, 2024 · The diglycolamide extractant T2EHDGA has proven to be promising for the separation of lanthanides and minor actinides in high-level nuclear waste reprocessing. …
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WebSep 11, 2024 · The complexation of HDEHP, HEH[EHP], T2EHDGA, and TODGA and mixtures thereof in n-dodecane with Nd(III), Pm(III), and Am(III), extracted from pH 3 aqueous media, were analyzed by distribution analysis, IR, UV–vis, and X-ray spectroscopies. Appreciable ternary complex formation is seen among HDEHP with DGA … WebJan 4, 2011 · (T2EHDGA, Fig. 1) N,N,N′,N′-tetra-2-ethylhexyldiglycolamide was procured from Thermax, India. Characterization of T2EHDGA was done by elemental analysis, … john o neill the jazz method for tenor audio
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WebSep 30, 2024 · Solvation analyses of T2EHDGA revealed expected amphiphilic behavior in pure solvent systems. In a nitric-acid-free biphasic solvent, it was found that T2EHDGA expressed similar interfacial conformations as HEHEHP, suggesting that a parallel-like configuration, relative to the interface, is adopted at low concentrations. WebSep 1, 2016 · According to the slope analysis results, there were two T2EHDGA molecules involved in Fe (III) extraction. From the result of [Cl −] concentration effect and UV–visible spectra, the stoichiometry of the chloride ions and Fe (III) in … WebMar 15, 2010 · The effect of phase modifiers, viz. N,N-di-n-hexyl octanamide (DHOA), tri-n-butyl phosphate (TBP) and isodecanol on the limiting organic concentration (LOC) of Nd was investigated. Minimum concentration of phase modifiers needed to avoid third phase formation for 0.1 M T2EHDGA was 5% iso-decanol, 20% TBP or DHOA. john only apostle not martyred